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Optics: A ray of light travels from glass (n = 1.5) into water (n = 1.33). What is the condition for Total Internal Reflection to occur?

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Acidity of Phenols & Resonance Stabilization
NEET / JEE Chemistry
Core Concept

Phenols are significantly more acidic than alcohols (pKa ≈ 9.95 vs 15.9) because the conjugate phenoxide ion is resonance-stabilized across the aromatic ring, delocalizing negative charge to ortho and para carbons.

Mechanism & Relative Order

Ka ≈ 1.3 × 10^-10 | Order: Picric Acid > 2,4-DNP > 4-Nitrophenol > Phenol > Ethanol

Examiner Trap Autopsy

Chlorine Trap: While resonance directs ortho/para in substitution, inductive (-I) effect dominates in phenol acidity. Hence o-chlorophenol is strictly MORE acidic than un-substituted phenol.

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